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Download e-book for iPad: Advances in Inorganic Chemistry, Vol. 41 by A. G. Sykes

By A. G. Sykes

ISBN-10: 0120236419

ISBN-13: 9780120236411

Advances in Inorganic Chemistry offers well timed and informative summaries of the present growth in quite a few topic parts inside inorganic chemistry starting from bio-inorganic to strong nation experiences. Thisacclaimed serial good points studies written by way of specialists within the region and is an fundamental connection with complex researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is totally referenced.

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Extra resources for Advances in Inorganic Chemistry, Vol. 41

Sample text

The six nitrogen atoms form a distorted trigonal prism monocapped by Br, which causes the two flanking dioximes to be spread away by about 20"toward the third dioxime ligand, thus probably precluding the addition of a second boron cap (2541. 4, which indicates that there may be a n equilibrium in uiuo between the neutral hydroxy and cationic aqua forms (24, 256, 257). Electrochemically, chloro and bromo BATOs undergo a n irreversible twoelectron reduction that appears to be biologically inaccessible (259).

9. The structure of the cation in [T~(tdt)(drnpe)~IPF~ (304). 1(4)",however, seem t o offer little distinction between neutral and anionic nitrogen. Cationic complexes of the type [TcCl2L1 have been prepared by the reaction of [TcCl,(PPh,),] with the tetradentate ligands (27) (310). + I. COMPLEXES WITH SULFUR LIGANDS Only complexes in which sulfur ligands form the major part of the coordination sphere are discussed here; other sulfur complexes are described under various headings. Most important is the homoleptic orange-red thiourea complex "l"c(tu),]Cl,, which precipitates in high yield from a concentrated HCUethanol solution containing TcO,- and thiourea (111).

A notable feature of this work is the use of the greater truns effect of Br compared with that of C1 in order to accomplish stereospecific synthesis. Ligand exchange of [TcBr,I2- with HC1 results in the cis/ fuc complexes for n = 2,3, and 4, whereas ligand exchange of [TcCl6I2with HBr yields the trunslmer isomers (3311. The force constants for all the [TcX,I'- complexes have been determined (334),and the IR and Raman spectra of the 10 [TcCl,,Br,-, 1'- ( n = 0-6) species, including the pure geometrical isomers, at 80 K have been completely assigned and supported by normal coordinate analysis.

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Advances in Inorganic Chemistry, Vol. 41 by A. G. Sykes


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